钪 | 周期表 | 赛默飞 | Thermo Fisher Scientific

Scandium • Transition Metal

Primary XPS region: Sc2p
Overlapping regions: Ta4p_3/2, Cd3d_5/2, N1s, Ge LMM, Se LMM
Binding energies of common chemical states:

Chemical state	Binding energy Sc2p_3/2
Sc metal	398.5 eV
Sc₂O₃	401.8 eV
ScO(OH)	402.7 eV

ScO(OH) referenced to Sc2p metal peak. Sc₂O₃ referenced to adventitious C1s peak at 284.8eV.

Experimental information

N/A

Interpretation of XPS spectra

Sc2p peak has significantly split spin-orbit components (Δ_metal=4.90eV).
- Splitting Δ-value varies with chemical state. (e.g., Δ_oxide=4.3eV for Sc₂O₃).
- For many elements, the FWHM for each spin-orbit component is the same, but for scandium, the Sc2p_1/2 component is broader than the Sc2p_3/2 peak.
Spectrum below has been assigned according to Ref [1].

References

[1] MC Biesinger et al., Applied Surface Science 257 (2010) 887-898.

About this element

Symbol: Sc
Date of discovery: 1878
Name origin: Latin Scandia
Appearance: silver
Discoverer: Lars Nilson
Obtained from: thortveitite, wiikite

Melting point: 1814 K
Boiling point: 3103 K
Density[kg/m³]: 2985
Molar volume: 15.00 × 10^-6 m³/mol
Protons/Electrons: 21
Neutrons: 24
Shell structure: 2,8,9,2
Electron configuration: [Ar]3d14s2
Oxidation state: 3
Crystal structure: hexagonal

A rare transition element, scandium was discovered in 1878 by L. Nilson in Scandinavia. It occurs in only trace amounts on earth, though it is much more abundant in the sun and other stars. Although scandium can develop a slightly yellow or pink tinge upon exposure to air, it exists in its standard state as a soft, silvery white metal. Scandium’s high melting point and lightweight characteristics make it of interest to the aerospace industry and designers of sports equipment. Current applications of scandium include use in bicycle frames and in the production of high intensity light when combined with oxygen.